Di-μ-chlorido-bis{[2-(di-tert-butylphosphanyl)biphenyl-3-yl-κ2 C 3,P]palladium(II)} dichloromethane disolvate
نویسندگان
چکیده
The asymmetric unit of the title compound, [Pd(2)Cl(2)(C(20)H(26)P)(2)]·2CH(2)Cl(2), contains one half-mol-ecule of the palladium complex and a dichloro-methane solvent mol-ecule. In the complex, two Pd(II) atoms are bridged by two Cl atoms, with the other two coordination sites occupied by a C atom of the biphenyl system and a P atom, resulting in a distorted square-planar coordination geometry of the Pd(II) atom and a cyclo-metallated four-membered ring. The Pd(2)Cl(2) unit is located about an inversion center. The planes of the rings of the biphenyl system make a dihedral angle of 66.36 (11)°.
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عنوان ژورنال:
دوره 69 شماره
صفحات -
تاریخ انتشار 2013